When charging Lithium (LiFePO4) batteries, temperature is critical. The commonly quoted -30°C to +80°C range applies only to discharging, not charging. Charging below 0°C (32°F) must be avoided, as it can cause lithium plating, a reaction that permanently reduces battery capacity and lifespan.
The optimal charging range is +5°C to +45°C (41°F to 113°F). To protect your battery in cold conditions, wait until temperatures rise, use a heated lithium battery, install batteries in warmer locations, or use a battery management system (BMS) that monitors temperature to prevent unsafe charging.
Charging lithium batteries in extreme temperatures
If you have a Lithium (LiFePO4) battery, there are some things to consider when charging under extreme temperature conditions.
Operational vs optimal temperature range
Lithium battery manufacturers often state an operational temperature range of -30°C to +80°C (-22°F to +176°F) and an optimal temperature range of -10°C to +50°C (14°F to 122°F). Temperatures can vary depending on brand and model, REDARC recommend consulting your manufacturer.
This is often misconstrued as a safe temperature range for both charging and discharging, this is not the case. The operational temperature range is referring to discharging the battery only.
Charging restrictions below 0°C / 32°F
Charging a lithium battery in ambient temperatures below 0°C / 32°F must be avoided. The reason for this is it may potentially damage the battery and / or reduce its lifespan.
Optimum charging temperature for lithium batteries
The optimum ambient temperature for charging a Lithium battery is +5°C to +45°C / 41°F to 113°F. When attempting to charge a Lithium battery below 0°C / 32°F a chemical reaction referred to as “Lithium Plating” occurs.
Lithium plating
Lithium plating is caused by the charge current forcing the lithium ions to move at a faster reaction rate and accumulate on the surface of the anode.
When this chemical reaction occurs, the internal resistance of the battery increases and reduces the rate of chemical metabolism. This chemical reaction causes a permanent reduction of the battery’s capacity and will continue to reduce its capacity each time this reaction occurs.
Preventing low-temperature charging damage
If you plan on using a Lithium battery in a location that may drop below 0°C / 32°F, you must be cautious as to when you attempt to charge the battery. Simply waiting for the temperature to raise during the day is a simple solution.
Having the batteries mounted in a location that will have a higher ambient temperature than outside temperature is also advisable.
Having a battery management system that can monitor the batteries temperature will be beneficial and convenient. With the touch of a button you can see what the standing temperature of the battery is and therefore whether it is safe to charge.